Liquids - When a chemical
agent is used for its liquid effect, evaporation causes the agent to
form into a vapor. Depending on volatility, vapor clouds, which tend
to stand near the surface because of high vapor density, are usually
of low concentration and have about the same temperature of the surrounding
air. Furthermore, vapor density governs the extent that the vapor will
mix with air. Persistence agents are those with high vapor density impact
at ground level with very little evaporation of the same, and while
drops are airborne, and after impacting, the liquid continues to evaporate.
The rate at which the liquid will evaporate at a given temperature and
pressure is governed by the agent vapor pressure. Initial concentrations
are lower, since the vapor source is not instantaneous as a vapor agent
is, but evolves over a long period until the liquid source is expended.
Liquid agents may be absorbed, being taken in through the pores of a
surface, and adsorbed, i.e., accumulated on a surface of a solid, and
they may also evaporate. Desorption, i.e., changing from an adsorbed
state to a gaseous state and going back into the air, begins as the
liquid is no more present on the surface. The vapor concentration over
areas contaminated with a liquid agent tends to be less than with newly
formed vapor clouds, and downwind agent concentrations are not nearly
as great as with other types of agents. |
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